N-(2-Hydroxyethyl)-3,5-dinitrobenzamide
نویسندگان
چکیده
The title compound, C(9)H(9)N(3)O(6), was synthesized by the condensation of methyl 3,5-dinitro-benzoate and 2-amino-ethanol. The non-centrosymmetric space group results in the formation of pseudo-chiral helices in the crystal structure, which exhibits a layer packing structure involving intra-molecular N-H⋯O and O-H⋯O inter-actions.
منابع مشابه
A co-crystal of 3-(3,5-dinitrobenzoyl)-1,1-dimethylthiourea and N,N-dimethyl-3,5-dinitrobenzamide
In the title compound, C(10)H(10)N(4)O(5)S·C(9)H(9)N(3)O(5), the amide groups of 3-(3,5-dinitro-benzo-yl)-1,1-dimethyl-thio-urea and N,N-dimethyl-3,5-dinitro-benzamide mol-ecules are oriented at dihedral angles of 39.13 (8) and 55.97 (11)°, respectively, to the attached benzene rings. In the crystal, the two mol-ecules are linked by an N-H⋯O hydrogen bond. Weak C-H⋯O link the mol-ecules into a ...
متن کاملN-Methyl-3,5-dinitrobenzamide
The asymmetric unit of the title compound, C(8)H(7)N(3)O(5), contains two independent mol-ecules in which the amide plane is oriented at dihedral angles of 29.82 (2) and 31.17 (2)° with respect to the benzene ring. In the crystal, mol-ecules are connected via inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.
متن کاملN-Ethyl-3,5-dinitrobenzamide
In the title mol-ecule, C(9)H(9)N(3)O(5), the dihedral angle between the mean planes of the amide group and the benzene ring is 31.24 (14)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules to form one-dimensional chains propagating in [100].
متن کامل4-(2-Hydroxyethyl)anilinium 3,5-dinitrobenzoate
In the title compound, C(8)H(12)NO(+)·C(7)H(3)N(2)O(6) (-), the anilinium and hydroxyl protons of the cation result in N-H⋯O, N-H⋯(O,O) and O-H⋯O hydrogen-bonding inter-actions with carboxyl-ate O-atom acceptors, forming a two-dimensional network structure. An intermolecular C-H⋯O interaction is also present.
متن کامل2-Methoxy-N-[(S)-3-methylbutan-2-yl]-6-{[(S)-3-methylbutan-2-yl]amino}-3,5-dinitrobenzamide
The title compound, C(18)H(28)N(4)O(6), crystallizes with two mol-ecules in the asymmetric unit which differ slightly in conformation. The dihedral angle between the amide plane and the benzene ring are 72.6 (2) and 66.8 (2)° in the two mol-ecules. A strong intra-molecular N-H⋯O hydrogen bond between the amino and nitro groups occurs in each mol-ecule. The crystal structure features two symmetr...
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